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Sorbent Information for C18, C18FF, C8

Bonded silica sorbents are commonly used for the solid phase extraction of analytes from complex sample matrices. A variety of functional groups, such as octadecyl (C18) and octyl (C8) can be bonded to the silica surface to provide non polar interactions. Each of these sorbents exhibits unique properties of retention and selectivity for a particular analyte. The choice of which sorbent is best for a particular method will be influenced by the percent recovery of analyte from the sample matrix and the cleanliness of the resulting chromatography.

Applications
EPA Approved Methods C18 C8
Safe Drinking Water Act 506, 508.1, 525.1, 525.2, 550.1, 1613B 549.1
Comprehensive and Environmental Response, Compensation, and Liability Act (CERCLA) Quick Turnaround Method (QTM) for Organochlorine Pesticides and PCBs  
Clean Water Act Method 608 Alternate Test Procedure 3M0222  
Clean Water Act - Effluent Guidelines for Pesticide Manufacturing 507, 508, 525.2, 608  
Resource Conservation Recovery Act (RCRA) 8061(2nd update), 8081 (3rd update)  

 

Sorbent Characteristics
  C18 C18FF C8
Bonded Functional Group Octadecyl Octadecyl Octyl
Retention Mechanism Strongly non polar Strongly non polar Moderately non polar
Endcapped Yes Yes Yes
Percent Carbon (avg.) 22.5 22.5 15.5
Pore Size (avg.) 60 Å 60 Å 60 Å
Average particle size 12 µm 45 µm 12 µm

 

Product Usage

The versatile Empore™ C18 and C8 products are effective for extracting semi-volatile and nonvolatile organic compounds.

  • Approved for use with numerous EPA Methods.
  • Empore™ Extraction Disks reduce pollution by reducing the solvent usage.
 

Chemical Structure

C18C18FFC8 Chemical Structure
3M Addresses